Crystal structure of bis(μ-2-benzoylbenzoato-κ2 O:O′)bis[bis(2,2′-bipyridine-κ2 N,N′)manganese(II)] bis(perchlorate)
نویسنده
چکیده
The title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl-benzoate ligands, each Mn(II) atom being further coordinated by two 2,2'-bi-pyridine (bipy) ligands in a distorted octa-hedral environment. Within the binuclear mol-ecule, the Mn⋯Mn separation is 4.513 (7) Å. Inter-molecular C-H⋯O and C-H⋯ π inter-actions link the mol-ecules into a three-dimensional network.
منابع مشابه
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In the crystal structure of the mononuclear title compound, [Mn(NCS)2(C10H8N2)2]·C10H8N2, the Mn(II) cation is coordin-ated in an all-cis configuration by two N-bound thio-cyanate anions and two 2,2'-bi-pyridine ligands within a slightly distorted octa-hedral environment. The asymmetric unit consists of one Mn(II) cation, two thio-cyanate anions and two 2,2'-bi-pyridine ligands, as well as two ...
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015